Portable ammonia factories could fuel clean cars - environment - New Scientist

FORGET hydrogen: ammonia could be the answer to developing an emissions-free fuel for cars.

Ammonia produces just nitrogen and water vapour when burned and, unlike hydrogen, it is relatively easy to store in liquid form. That means transporting ammonia will not require costly new infrastructure, says John Fleming of SilverEagles Energy in Lubbock, Texas.

Fleming and Tim Maxwell at Texas Tech University, also in Lubbock, are developing a system to produce ammonia that can be installed in filling stations. Powered by mains electricity, it first produces hydrogen from water using electrolysis, then combines it with nitrogen from the air to produce ammonia.

To achieve this, the researchers have adapted the Haber-Bosch process used to make ammonia industrially. Their version works on a small scale and can make ammonia fairly cheaply.

In their system, a piston rapidly compresses hydrogen and nitrogen, heating the gases to 400 °C. The mixture is fed into a chamber containing an iron oxide catalyst, which sparks a reaction that further heats the gases and generates ammonia. In a third chamber, the mixture decompresses and cools down to room temperature. As it does so, it pushes against another piston, from which mechanical energy is recovered and fed back to the compressor, significantly cutting the process's power consumption.

Finally, a heat pump cools the mixture down to around -75 °C, liquefying the ammonia for collection.

The team say the whole system could fit within a standard container and could therefore be transported by truck for installation at filling stations, where it could make between 4000 and 40,000 litres of ammonia per day. Maxwell adds that the system has a modular design, so it can easily be scaled up to produce more. The ammonia could be made for just 20 cents per litre, they claim.

Edman Tsang, a chemist at the University of Oxford, says that a mobile unit that can turn water and electricity from renewable energy sources into fuel ammonia would be useful in remote areas. Fleming and Maxwell are already working with the US army and air force, who have each expressed interest in using the technology on the battlefield.

However, Tsang is not convinced that the hydrogen needed to make ammonia can be produced economically using electrolysis. Fleming and Maxwell claim to have got round this hurdle, too (see "Hydrogen on the cheap").

Conventional cars can already make use of ammonia - they can run on a mixture that is 90 per cent gasoline and 10 per cent ammonia, says Fleming. So-called flexible-fuel vehicles, which use a mixture of gasoline and ethanol, could also be modified to run on a fuel that is up to 85 per cent ammonia. Such vehicles have sensors that constantly detect the exact proportion of gasoline and ethanol being fed through, and adjust their fuel injection and spark timing accordingly. To run on ammonia, the vehicles would need to be reprogrammed and equipped with a fuel tank capable of storing ammonia under pressure.

The team are also designing an engine that could run purely on ammonia. Called the Linear Electric Internal Combustion Engine, it is based on an existing design, known as a free piston engine, in which the burning air and ammonia mixture moves a piston forwards and backwards. This is used to drive a generator, the electricity from which powers a motor that turns the wheels.

Hydrogen on the cheap

A device being developed by John Fleming of SilverEagles Energy and Tim Maxwell from Texas Tech University could halve the cost of making hydrogen by electrolysis.

Conventional electrolysis units are made up of more than 100 2-volt cells connected in series, ensuring they can be powered by a 240-volt mains electricity supply. By using a transformer-like device to step the mains voltage down to 1.75 volts, Fleming has been able to simplify the design to use just eight cells. This makes the units much cheaper to manufacture and operate.

The pair claim their design can produce hydrogen at $2.80 per kilogram, compared to $5.20 per kg for conventional electrolysis units.

Production of Carbon Free Liquid Fuel and Fertilizer

Future economic prosperity is greatly dependent upon future sources of energy. Research underway at Texas Tech University is pioneering new technologies based on the Nitro-Hydrogen Economy. The Nitro-Hydrogen Economy provides a low-cost, carbon free, liquid fuel and fertilizer at point of sale. The fuel can be blended with gasoline and/or diesel for use in existing vehicles at up to 85% (15% gasoline). The development of advanced engine technologies will provide overall vehicle efficiencies on a par with battery electric technology. The technology is being developed by an interdisciplinary program at TTU.

Key highlights of this technology include:

• Carbon free liquid fuel and fertilizer produced at point of sale from renewable electricity at $1.35/gal
• No need to transport fuel
• Makes more effective use of the existing electrical grid to provide 75% of current gasoline usage
• No need for massive and costly new infrastructures
• Provides controllable storage of electricity: used as fuel, fertilizer, or recycled back to electricity
• Storage Increases utilization of wind, solar and renewable sources by approximately 30% and helps balance the electrical grid
• Provides US energy security by removing dependence on foreign Oil
• Provides major reduction in Carbon Dioxide, Oxides of Nitrogen and other pollutants
• Assists economic recovery by eliminating $300 Billion per year of offshore payments while providing US jobs

NH3 can be liquefied, a solution in part for safety. Small processors solve the transport and distribution issues in a major way. The Texas Tech effort seems to be closing in on the production cost, too. That leaves the storage matter – a problem looking for solutions more likely answered by demand for engineering than research.
One would think that an economy faced with a fundamental need for very cheap energy supplies would move more hastily towards a very low cost source that bypasses the hydrogen era and goes directly to a nitrogen-hydrogen economy.

The motives are very basic. Cheap. Limitless. No carbon. 
Think about it.

4 NH3 + 3 O2 → 2 N2 + 6 H2O (g) (ΔHºr = –1267.20 kJ/mol) 
 About half the energy density of diesel.